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All unusuals ever owned:

All info was found from Tf2items historical data, which doesnt let me go back to my very very first unusuals, sadly. So it starts from Nov 24th, 2010.
=?=
0. First Unusual, Purple Confetti Sergeant's Drill Hat (Or possibly Green Confetti Stovepipe, dont remember 100%)

=2010=
1. Searing Plasma Ze Goggles (Nov 24th)- 1 Unusual
2. Purple Energy Old Guadalajara (Nov 25th)- 1 Unusual
3. Green Energy Vintage Merryweather (Nov 28th)- 1 Unusual
4. Purple Energy Ye Olde Baker Boy (Dec 11th)- 1 Unusual
5. Scorching Flames Pyro's Beanie (Dec 16th)- 2 Unusuals
6. Scorching Flames Pyromancer's Mask (Dec 18th)- 2 Unusuals
7. Burning Flames German Gonzilla (Dec 20th)- 2 Unusuals
8. Purple Energy Glengarry Bonnet (Dec 20th)- 2 Unusuals
9. Burning Flames Prussian Picklehaube (Dec 21st)- 3 Unusuals
10. Burning Flames Magnificent Mongolian (Dec 21st)- 3 Unusuals
11. Scorching Flames Dr's Dapper Topper (Dec 22nd)- 3 Unusuals
12. Massed Flies Blighted Beak (Dec 22nd)- 3 Unusuals
13. Burning Flames Old Guadalajara (Dec 24th)- 3 Unusuals
14. Sunbeams Chieftain's Challenge (Dec 25th)- 3 Unusuals
15. Green Energy Noble Amassment of Hats (Jan 1st)- 3 Unusuals
16. Green Energy A Rather Festive Tree (Jan 2nd)- 3 Unusuals
17. Sunbeams Madame Dixie (Jan 7th)- 3 Unusuals (Holy cancer)
18. Haunted Ghosts Le Party Phantom (Jan 8th)- 3 Unusuals
19. Scorching Flames Demoman's Fro (Jan 9th)- 5 Unusuals
20. Haunted Ghosts Vintage Merryweather (Jan 9th)- 5 Unusuals
21. Purple Confetti Dr's Dapper Topper (Jan 9th)- 5 Unusuals
22. Green Confetti Tippler's Tricorne (Jan 11th)- 5 Unusuals
23. Burning Flames Hound Dog (Jan 12th)- 4 Unusuals
24. Scorching Flames Hotrod (Jan 18th)- 4 Unusuals
25. Purple Confetti Tippler's Tricorne (Jan 27th)- 4 Unusuals
26. Sunbeams Napper's Respite (March 3rd)- 3 Unusuals
=2011=
27. Burning Flames Batter's Helmet (Dec 23rd)- 3 Unusuals
=2012=
28. Sunbeams Tyrant's Helm (March 16th)- 3 Unusuals
29. Haunted Ghosts Vintage Tyrolean (March 16th)- 3 Unusuals
30. Blizzardy Storm Tough Guy's Toque (March 16th)- 3 Unusuals
31. Purple Confetti Dr's Dapper Topper (July 2nd)- 5 Unusuals
32. Burning Flames Tippler's Tricorne (July 2nd)- 5 Unusuals
33. Scorching Flames Big Elfin Deal (July 3rd)- 7 Unusuals
34. Bubbling Tyrants Helm (July 3rd)- 7 Unusuals
35. Blizzardy Storm Backwards Ballcap (July 3rd)- 7 Unusuals
36. Burning Flames Troublemaker's Tossle Cap (August 2nd)- 4 Unusuals
??. Vivid Plasma Whoopee Cap (Good times)
=2013=
37. Harvest Moon Sergeant's Drill Hat (?)- 4 Unusuals
38. Burning Flames Anger (February 4th)- 1 Unusual
39. Burning Flames Flamboyant Flamenco (June 5th)- 1 Unusual
=2014=
40. Hellfire Hong Kong Cone (June 30th)- 1 Unusual